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Abstract

A new organic-inorganic hybrid with the empirical formula [NH3-CH2-COOH]CdCl3 center dot H2O has been crystallised, and the structure was solved at room temperature (system (orthorhombic), space group (Pcam), unit parameters cell (a = 7.433(10) angstrom, b = 7.743(2) angstrom, c = 25.346(6) angstrom), volume 1458.76 (5) angstrom(3)), Z = 8). The asymmetric unit cell consists of a combination of Cd-0.5 Cl-3 anions, one organic +NH3(CH2)CO2H cations, and one water molecule to form a two-dimensional perovskite system. The hydrogen-bonding network ensures cohesion between these layers. The micro-Raman spectroscopy measurement technique is used to probe organic-inorganic halide perovskite vibration modes. The compound was, also, characterised using the vibrating sample magnetometer VSM and the UV-visible absorption techniques. (C) 2020 Elsevier B.V. All rights reserved.

Authors

Kaiba, A.;  Geesi, Mohammed H.;  Guionneau, P.;  Riadi, Yassine;  Aljohani, Talal A.;  Elsanousi, Ammar;  Ouerghi, Oussama

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