A discrete hexagonal metallacycle 1 decorated with tetraphenyl-ethylene, amide groups and long hydrophobic alkyl chains was constructed via [3+3] coordination-driven self-assembly, from which the fluorescence emission-enhanced organogelator with multiple stimuli-responsiveness was successfully prepared via hierarchical self-assembly.
Hierarchical self-assembly of a fluorescence emission-enhanced organogelator and its multiple stimuli-responsive behaviors
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