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Abstract

In this study, we used a compositionally gradient anode functional layer (AFL) consisting of Ni-BaCe0.5Zr0.35Y0.15O3-delta (BCZY) with increasing BCZY contents toward the electrolyte -anode interface for high-performance protonic ceramic fuel cells. It is identified that conventional homogeneous AFLs fail to stably accommodate a thin film of BCZY electrolyte. In contrast, a dense 2 mu m thick BCZY electrolyte was successfully deposited onto the proposed gradient AFL with improved adhesion. A fuel cell containing this thin electrolyte showed a promising maximum peak power density of 635 mW cm(-2) at 600 degrees C, with an open-circuit voltage of over 1 V. Impedance analysis confirmed that minimizing the electrolyte thickness is essential for achieving a high power output, suggesting that the anode structure is important in stably accommodating thin electrolytes.

Authors

Bae, Kiho;  Lee, Sewook;  Jang, Dong Young;  Kim, Hyun Joong;  Lee, Hunhyeong;  Shin, Dongwook;  Son, Ji-Won;  Shim, Joon Hyung

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